Lithium-ion conductivity and crystallization temperature of multicomponent oxide glass electrolytes

Abstract

Lithium-ion-conducting oxide glass electrolytes in the multicomponent systems Li 2 O–B 2 O 3 –SiO 2 –P 2 O 5 -LiX (LiX = Li 3 N, Li 2 SO 4 , Li 2 CO 3 , and LiI) were synthesized using a mechanochemical technique. The crystallization temperature and ionic conductivity of multicomponent glasses with added lithium salts or Li 3 N were evaluated. Because the crystallization temperature is a measure of the ability of glasses to resist crystallization at high temperature, glasses with high conductivity and high crystallization temperature are desirable electrolytes. In this study, the lithium-ion conductivity of the glasses was found to be correlated with the crystallization temperature, and it was difficult to increase both the conductivity and crystallization temperature. The addition of lithium salts (Li 2 SO 4 , Li 2 CO 3 , and LiI) increased the conductivity but decreased the crystallization temperature. Nitrogen doping by the addition of Li 3 N improved both these properties of the oxide glass electrolyte. Therefore, oxynitride glasses are desirable electrolytes owing to their thermal stability and lithium-ion conductivity. • Li 2 O-based multicomponent oxide glasses are prepared via mechanochemistry. • Lithium ion conductivity of glasses is correlated with crystallization temperature. • The addition of lithium salts increases conductivity but decreases thermal stability. • Nitrogen-doping to oxide glasses improves both those properties.