Abstract
The title compound, poly[[(acetonitrile)lithium(I)]-μ-triflato], [Li(CF3O3S)(C2H3N)]∞, was synthesized by reaction of LiCF3SO3 with CH3CN and is found to exist as a one-dimensional polymer in the solid state. Each Li+ cation is tetrahedrally coordinated by three oxygen donors from three different CF3SO3− anions [Li—O = 1.925 (3), 1.926 (3) and 1.940 (2) Å] and one CH3CN nitrogen donor [Li—N = 2.042 (3) Å]. The unit cell has a β angle of 90.064 (3)°, but the Laue symmetry is 2/m. As a result of this, the crystals exist as pseudo-merohedral twins related by the twin law (\overline 100/0\overline 10/001).
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