Lithium systematics in howardite–eucrite–diogenite meteorites: Implications for crust–mantle evolution of planetary embryos

Abstract

We present lithium (Li) abundances and isotope compositions in a suite of howardites, eucrites and diogenites (HEDs). These meteorites most likely originated from asteroid Vesta and were delivered to Earth by a series of independent impact events. The Li concentrations show striking differences between Li-poor diogenites plus cumulate eucrites and Li-enriched eucrites whilst howardites have Li abundances intermediate between eucrites and diogenites. Contrary to Li elemental inter-group differences, Li isotope compositions are irresolvable among these individual groups of HED meteorites despite their wildly distinct petrography, attesting to insignificant Li isotope fractionation during formation of a thick basaltic crust by melting of the Vestan mantle. The mean Li isotope composition of Bulk Silicate Vesta is estimated at 3.7±0.6‰ (1σ), intermediate to that of the Earth versus Mars and Moon but identical with these terrestrial bodies within uncertainty. This further validates largely homogeneous inner Solar System solids from the Li isotope perspective and supports the lack of loss of moderately volatile elements from planetary embryos during their magmatic histories because Li does not follow depletion trends inferred from more volatile elements. Pasamonte eucrite has the same Li isotope composition as other eucrites although it may not be directly linked to Vesta. These observations are also important for generating Li elemental and isotope signatures in juvenile basaltic crusts of large terrestrial planets and numerous planetary embryos in the early Solar System. A combination of CV+L chondrites may be less suitable for building Vesta from Li perspective but this may face sampling bias of available data and only further analyses may resolve this issue. Alternatively, significant shift of ∼1‰ towards heavier Li isotope compositions must have occurred during thermal processing of CV+L (2.2–2.8‰) mixture in order to account for the observed Li isotope systematics in HED meteorites. No correlation is observed between Li versus Zn, Fe or Si isotopes, respectively, implying unrelated processes of forming stable isotope variations observed in HED meteorites.