Abstract

Cycleability performance of ‘tailor-made’ poly( N-oxyalkylpyrrole) electrodes in solid-state lithium cells with poly(ethylene oxide) (PEO)-based electrolyte are compared with that of poly(N-butylpyrrole) and poly(pyrrole) electrodes. The specific effect of ether groups in improving the ionic transport in the polymer electrodes was demonstrated by determining the ion diffusion coefficients from analysis of the impedance spectra.

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