Abstract
We present the structural (XRD and Raman) and electrochemical properties of various oxides of the cobaltate family (with the α-NaFeO 2-type structure) grown by solid-state reaction, wet chemistry and film deposition techniques. It is shown that synthesis greatly affects the electrochemistry and cycle life characteristics of these layer structured cathode materials. HT-LiCoO 2, LT-LiCoO 2, doped LiCo 1− y Al y O 2 and LiCoO 2 films are investigated.
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