Abstract

An efficient and low-cost spectroscopic tool, photoacoustic spectroscopy (PAS), is described. Although this tool is suitable for all levels of chemistry and physics laboratories, it is particularly useful in an undergraduate laboratory. PAS is an excellent technique for studying the optical absorption spectra of opaque and highly light-scattering substances such as nanomaterials. It also has the capability of obtaining the depth profiles of crystals and thin films. Unlike in the conventional absorption and fluorescence spectroscopic techniques, PAS monitors the pressure changes in the gas medium surrounding the sample owing to the heat generated as a result of nonradiative deexcitation following optical absorption. The technique virtually requires no sample preparation. A few examples to demonstrate the usefulness of this tool are given. Fundamental knowledge on spectroscopic techniques like PAS will be an asset to those students who opt for graduate studies or those students who go on to a career in industry.

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