Abstract
The distribution of divalent manganese, cobalt, copper, zinc and cadmium between aqueous solutions of hydrochloric acid and/or lithium chloride and the solutions of tricaprylmethylammonium chloride (Aliquat-336, R 3R′NCl) in benzene has been investigated under different conditions. It is found that the extraction of these metals by Aliquat-336 proceeds as MCl 4 2−(aq) + 2 R 3R′NCI(org) ⇌ (R 3R′N) 2MCI 4 (org) + 2 Cl −(aq). The extraction curves have been examined utilizing a modified chemical model on the basis of this equilibrium equation. In addition, the electronic, electron spin resonance and infrared spectral results suggest that all the complexes formed in the organic phases are in a tetrahedral arrangement.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.