Liquid-Infused Membranes Exhibit Stable Flux and Fouling Resistance.

Abstract

Antifouling membranes that offer excellent operational lifetimes are critical technologies needed to meet the growing demand for clean water. In this study, we demonstrate antifouling membranes featuring an ultrathin oil layer that stayed immobilized on the surface and in the pore walls of poly(vinylidene fluoride) membranes for multiple cycles of operation at industrially relevant transmembrane pressures. An optimized quantity of a commercial Krytox oil with either a low (K103) or a high viscosity (K107) was infused onto the active surface and into the pores of membranes with a 0.45 μm pore size. The presence of the oil layer was qualitatively confirmed using crystal violet staining and variable pressure scanning electron microscopy. Using a dead-end stirred cell, a consistent pure water permeance value of 3000 L m-2 h-1 bar-1 was achieved for the K103 liquid-infused membranes for at least 10 operation cycles, which was expectedly lower than the permeance of bare control membranes (∼16 000 L m-2 h-1 bar-1), suggesting that a stable oil layer was formed on all membrane-active sites. To quantify if oil was lost during membrane operation, extensive thermogravimetric analysis was conducted on both the as-prepared and used membranes. When challenged with the microorganism, Escherichia coli K12, the liquid-infused membranes statistically reduced microbial attachment by ∼50% versus the control membranes. For the first time, we have demonstrated that by forming an immobilized, robust, and stable oil-coated membrane, we can generate high-performance membranes with stable permeance values that can be operated at relevant transmembrane pressures and provide long-lasting antifouling properties.