Liquid–solid phase equilibria and the frozen ratio of ternary aqueous solution of acetic acid and sodium chloride

Abstract

ABSTRACTIn this study, we obtained the liquid–solid phase diagrams of a ternary solution of sodium chloride, acetic acid, and water, and a diagram of the frozen ratio of this ternary mixture. Based on the data from differential scanning calorimetry (DSC) measurement, the phase equilibria of this ternary system were successfully visualized. The formation of the ternary eutectic phase occurred between −34°C and −35°C, and the formation of the binary eutectic phase was suggested around −22°C to −34°C. Higher concentrations of a component had a significant effect on the phase equilibrium. A diagram of the frozen ratio of the ternary solution of sodium chloride at −20°C was also obtained by a simple temperature measurement method. This diagram is useful for estimating the ice fraction at the phase equilibrium of a frozen food system containing sodium chloride and acetic acid.