Abstract
New models of the process of cyclohexane oxidation in the liquid phase, including both reaction kinetics and mass transfer, are presented. The models have been used for the simulation of the industrial process in order to determine the influence of the hydrodynamic factors on the conversion and selectivity. The results of simulation are compared with the industrial data (CYCLOPOL process). Good agreement with experimental data was obtained using kinetic models comprising the free radical formation stages.
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