Abstract
AbstractLiquid state self‐assembly is important for the understanding of the complex structures developed in abiogenesis and biogenesis as well as for numerous potential technological applications. Herein we report the first body‐centered cubic liquid crystalline phase with 8‐connected network topology and open octahedral network structure. It is formed by dynamic soft self‐assembly of X‐shaped polyphiles with oligo(para‐phenylene‐ethynylene) cores. The π‐conjugated rods with perfluorinated inner benzene rings form networks conjoined by eight‐way junctions, which are formed by nano‐segregated spheres involving hydrogen‐bonded polar end groups, while the branched aliphatic chains at opposite sides of the cores fill the continuum. This novel cubic phase is based on the I‐WP minimal surface separating the frameworks of polyaromatic cores from the most disordered chain segments. It can also be considered as a dense sphere packing. Such liquid organic frameworks, representing hybrids of sphere packings and networks could be of interest for organic photonics and other technologies.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
