Abstract
A nitrobenzene extract of the ion-pair consisting of 8-quinolinol-5-sulfonate (Hqs −) and the cation of zephiramine (Z +Cl −, benzyldimethyltetradecylammonium chloride) was used as an ion-exchanging liquid membrane for the electrode responding to Hqs − ion. The potential response showed the Nernstian slope with the Hqs − activities varying from 10 −2 to 10 −4.5 mol l −1. The break points in the potential-pH plot with the constant analytical concentration of H 2qs correspond to the values of the negative logarithm of the acid dissociation constant of H 2qs. The present electrode was successfully applied to the potentiometric titration of copper(II) with H 2qs.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
