Abstract

Mutual solubilities of 3-methyl-2-butanone and water determined analytically for temperatures from −8 to 180°C at low pressure and from −8 to 90°C at pressures up to 350 MPa are reported together with ternary miscibility data at 0°C and 40°C and ambient pressure for the system 3-methyl-2-butanone-water-propanone. The results obtained do not support earlier reports that 3-methyl-2-butanone/water mixtures show two upper critical solubility pressures and one lower critical solubility pressure in an open miscibility loop but, rather, suggest solubility behaviour no different in kind from that of closely similar systems.

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