(Liquid + liquid) equilibria for ternary mixtures of (alkane + benzene + [EMpy] [ESO 4]) at several temperatures and atmospheric pressure

Abstract

In this work, the separation of benzene from aliphatic hydrocarbons (hexane, or heptane) is investigated by extraction with 1-ethyl-3-methylpyridinium ethylsulphate ionic liquid, [EMpy][ESO 4]. (Liquid + liquid) equilibria (LLE) data are determined for the ternary systems: {hexane (1) + benzene (2) + [EMpy][ESO 4] (3)} at T = (283.15, 293.15, 298.15, and 303.15) K and {heptane (1) + benzene (2) + [EMpy][ESO 4] (3)} at T = (283.15 and 298.15) K and atmospheric pressure. The selectivity and distribution coefficient, derived from the tie line data, were used to determine whether the ionic liquid is a good solvent for the extraction of aromatic from aliphatic compounds. The consistency of the tie line data was ascertained by applying the Othmer–Tobias and Hand equations. The experimental results for the ternary systems were well correlated with the NRTL equation. A study of the temperature effect and the influence of the chain length of the alkanes were realized. The results obtained were compared with other ionic liquids. There are no literature data for the mixtures discussed in this paper.