Abstract
Among the three components of the liquid junction potential at a junction between different solvents, the component due to the differences in electrolyte concentrations (or activities) on the two sides of the junction and the differences between the cationic and anionic mobilities was investigated. An equation was derived for the component at a junction with the same electrolyte (MX) on the two sides, ▪ where t represents the ionic transport numbers and a the electrolyte activity. Linear variations of t and a were assumed at the interphase region of the junction. The equation was confirmed experimentally to be approximately valid in many cases and may be used in estimating the component. In some cases, apparent deviations from the equation were observed. The deviations were attributed to the influence of electrolyte concentration, which caused partial decreases in the component due to the solvent-solvent interactions at the junction. Some theoretical and experimental studies were also carried out for a junction with different electrolytes (MX and NY) on the two sides, ▪
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
