Abstract

An asymptotic analysis of a boundary-value problem of the Boltzmann equation for small Knudsen number is carried out for the case when an unsteady flow of polyatomic vapour induces reciprocal evaporation and condensation at the interface between the vapour and its liquid phase. The polyatomic version of the Boltzmann equation of the ellipsoidal statistical Bhatnagar–Gross–Krook (ES-BGK) model is used and the asymptotic expansions for small Knudsen numbers are applied on the assumptions that the Mach number is sufficiently small compared with the Knudsen number and the characteristic length scale divided by the characteristic time scale is comparable with the speed of sound in a reference state, as in the case of sound waves. In the leading order of approximation, we derive a set of the linearized Euler equations for the entire flow field and a set of the boundary-layer equations near the boundaries (the vapour–liquid interface and simple solid boundary). The boundary conditions for the Euler and boundary-layer equations are obtained at the same time when the solutions of the Knudsen layers on the boundaries are determined. The slip coefficients in the boundary conditions are evaluated for water vapour. A simple example of the standing sound wave in water vapour bounded by a liquid water film and an oscillating piston is demonstrated and the effect of evaporation and condensation on the sound wave is discussed.

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