Abstract

In the present work, the Mn doped benzimidazole (BMZ) thin films were prepared by simple chemical bath deposition technique. The material was directly deposited as thin film on glass substrates and the metal concentration in the solution was varied in weight percentage in order to investigate the dopant effect on the properties of thin films. Similarly, the Mn doped BMZ films were deposited in different solution temperature to study the effect of deposition temperature on the properties of thin films. The PXRD and FT-IR spectroscopy are used to study the structural and the presence of functional groups in the BMZ medium. Depending upon the solution temperature, thickness of the films varying from 0.6 to 1.2 {\mu}m and the optical transparency of the samples increases with the increasing temperature up to 50 {\deg}C. Second Harmonic Generation (SHG) efficiency of the films is measured for all the films. Third order nonlinear optical properties of the films were analyzed using Z-scan technique. The experimental results show that Mn doped BMZ films exhibits saturation absorption and negative nonlinearity.

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