Abstract
A method for deriving Lorentzian line shape parameters (line strengths and halfwidths) from absorption spectra taken at two different path lengths is discussed. Far i.r. absorption spectra of carbon monoxide are analysed to yield line strengths and halfwidths for the rotational transitions J″ = 3 through J>″ = 9. Experimental errors are discussed, and the value for the dipole moment derived from the line strengths, 0·108±0·005 D, is in agreement with the microwave value within experimental uncertainty. The Lorentzian halfwidths are compared, where appropriate, with two recent determinations of these quantities. Lorentzian halfwidths are also derived from absorption spectra taken at long path length using theoretical line strengths based upon μ co = 0·112 D.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of Quantitative Spectroscopy and Radiative Transfer
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.