Abstract
Abstract Measurements of densities of solution of AgNO3 and Ca(NO3)2 in the mixed solvents water–methanol and water–acetonitrile were carried out at 25°C and the partial molar volumes V2∞ of these electrolytes were determined by taking account of the concentration dependence of the apparent molar volumes predicted by the Debye–Huckel theory. The ionic partial molar volumes of Ag+, Ca2+, and NO3− were evaluated and compared with those of other ions in the two mixed solvent systems. The solvent composition dependence is more remarkable in water–acetonitrile than in water–methanol, and characteristic behavior was observed for Ag+ and Ca2+ ions in water–acetonitrile system.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.