Abstract
Different kinetic equations for the description of a reversible photochemical and superimposed thermal reaction were evaluated. This kinetic analysis yielded reaction constants, which may have no physical significance and depend on the chemical system examined. To examine the influence of relative rates, temperature and spectral properties of the compounds on the quality of the evaluation, both exact and noisy test data sets were generated by using assumed reaction constants, relative ratios of absorptivities and various experimental conditions. As a consequence, the information gained was then applied to experimental data measured for a photochromic system (dihydroindolizine—betaine). Finally, we drew conclusions regarding the optimal experimental conditions and estimated the numerical significances of the data.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Photochemistry & Photobiology, A: Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
