Abstract
This manuscript reports on batch and column water-treatment experiments to remove fluoride using limestones from various geological rock formations (KIT1, KIT2, and KSS). The experiments evaluated removal efficiency and its relation with CaCO3 content and particle size (63–125μm, 300–600μm, and 840–1410μm). The results showed an efficient removal ability between 60% and 65%, which indicates that these materials may be used to treat fluoride-contaminated water or as part of a treatment system. The physico-chemical conditions for fluorite formation and precipitation were also evaluated, due to the natural presence of the F−/CaCO3 geochemical system. Possible removal mechanisms were evaluated through adsorption isotherms, saturation index (SI) calculations, and precipitation experiments within F−/Ca2+ systems. The concentration profiles along the columns with time indicated the occurrence of various sorption/desorption processes that may involve the formation of external sphere complexes. Batch experiments carried out to evaluate adsorption and feasibility of fluorite precipitation showed that the F−/CaCO3 ratio may be used to explain the removal mechanisms and the precipitation of CaF2 formation that occur in bulk solutions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.