Abstract

A pyrolysis oil obtained from the fast pyrolysis of poplar wood was subjected to mild hydrolysis and an aqueous and a non-aqueous fraction recovered. The non-aqueous fraction (pyrolytic lignin), a brown powder, was 23% of the oil, or 16% of the wood, corresponding to about 80% volatilization of the lignin content. Nuclear magnetic resonance spectra of this pyrolytic lignin were obtained, and its structure appears to be very similar to that of steam exploded poplar lignin. Methoxy content is relatively high and syringyl units appear to predominate over guaiacyl units. The pyrolytic lignin appears to be somewhat more degraded than steam exploded lignin and is probably lower in molecular weight.

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