Abstract

AbstractAn isotactic and an atactic polymethylmethacrylate have been investigated by light scattering measurements at 25°C in acetone/benzene mixtures in order to see the effects of the difference in the microstructures between the two stereoisomers on the preferential solvation and some other molecular parameters of the polymers. The extreme differences due to the structural effects between the stereoregular and the stereoirregular polymers appear in the mixed solvents with higher content of acetone.

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