Abstract

The light-induced drift (LID) of CH 3F molecules under vibrational excitation by a cw CO 2 laser has been investigated experimentally. The frequency dependence of the LID effect has been studied. The characteristic feature of this dependence (the effect is zero at the absorption line center) proves that the phenomenon observed is associated solely with the LID. The effect has been detected in 13CH 3F + 12CH 3F mixture with the fractionation coefficient of the gas mixture components equal to 1.7. The LID effect has been studied in CH 3F + H 2, CH 3F + He mixtures. A relative variation in the transport cross-section at vibrational excitation of CH 3F has been determined.

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