Light absorption enhancement in dye-sensitized solar cells using thin nanostructured photoelectrodes

Abstract

As thin-film solar cells are the attraction of many research works nowadays, dye-sensitized solar cells (DSSCs) among other types hold the promise of excellent cost/performance ratio because of the relatively low material costs and simple processing conditions. In order to improve its relatively low performance, different approaches are being explored to enhance the photon-to-current conversion efficiency. Notably, one of the most accessible approaches is by modifying the optical characteristics of the photoelectrode of DSSCs to improve light trapping within the cell. Here, we introduce a cost-effective nanopatterning process done on the photo-active TiO2 photoelectrode layer for better light absorption. This simple technique resulted in increased cell short-circuit current density (from 4.664 to 5.963 mA/cm2) which consequently enhanced cell efficiency (from 2.243 to 2.819%). Furthermore, without compromising the absorption significantly, nanopatterned photoelectrodes with a smaller thickness can lead to reduced material costs and possibly allowing the construction of semitransparent cells. This work can contribute to an attainable efficient DSSC manufacturing route for practical applications.