Abstract
Recent ENDOR measurements of transferred hyperfine interactions in the linear structure M3+-F--Cd2+, where M3+=Fe3+ or Cr3+ and the host lattice is CsCdF3, have given anomalous results when interpreted by standard ligand hyperfine structure theory. The data have therefore been reinterpreted allowing for polarisation of the F- ligand by the electric field from its neighbours. This is found to improve agreement between theory and experiment, especially if the fluoride ion is allowed to relax towards the M3+ ion, but some difficulties still remain.
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