Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66)

Maw Lin Foo,Susumu Kitagawa,Yoshiki Kubota,Yuh Hijikata,Tomohiro Fukushima,Masaki Takata,Satoshi Horike

doi:10.1039/c2dt31195j

Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66)

Maw Lin Foo, Susumu Kitagawa + Show 5 more

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https://doi.org/10.1039/c2dt31195j

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Journal: Dalton Transactions	Publication Date: Jan 1, 2012
Citations: 171	License type: other-oa

Affiliation: Kyoto Research Park, Japan Science and Technology Agency, Kyoto University, Osaka Prefecture University, Japan Synchrotron Radiation Research Institute, SPring-8

#Porous Coordination Polymer #Ligand-based Approach + Show 8 more

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Abstract

By adopting a ligand-based solid solution approach, the sulphonic acid functional group can be successfully incorporated into a porous coordination polymer with UiO-66 structure type. Zr(6)O(4)(OH)(4)(BDC-SO(3)H)(1.1)(BDC)(4.9) possesses enhanced heat of adsorption for carbon dioxide and acetone compared to Zr(6)O(4)(OH)(4)(BDC)(6).

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