Abstract
Lifetime measurements of theC3Δ electronic state of the titanium sulfide molecule and of theE3Π electronic state of the titanium oxide molecule have been performed using population probing with resonant two-photon ionization in a molecular beam. The lifetimes for the TiSC3Δ1state were found to be 243 ± 7 ns, 278 ± 9 ns, and 286 ± 15 ns for thev= 0,v= 1, andv= 2 levels, respectively. The lifetime for the TiOE3Π0state was found to be 4.9 ± 0.2 μs for thev= 0 level.
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