Abstract
Single crystals of trilithium(I) aluminium(III) bis[dioxidomolybdenum(VI)] dioxide bis[arsenate(V)], Li3AlMo2As2O14, have been prepared by solid-state reaction at 788 K. The structure consists of AsO4 tetrahedra, AlO6 octahedra and Mo2O10 groups sharing corners to form a three-dimensional framework containing channels running respectively along the [100] and [010] directions, where the Li+ ions are located. This structure is compared with compounds having (MX 2O12)n chains (M = Mo, Al and X = P, As) and others containing M 2O10 (M = Mo, Fe) dimers.
Highlights
Single crystals of trilithium(I) aluminium(III) bis[dioxidomolybdenum(VI)] dioxide bis[arsenate(V)], Li3AlMo2As2O14, have been prepared by solid-state reaction at 788 K
The structure consists of AsO4 tetrahedra, AlO6 octahedra and Mo2O10 groups sharing corners to form a three-dimensional framework containing channels running respectively along the [100] and [010] directions, where the Li+ ions are located
This structure is compared with compounds having (MX2O12)n chains (M = Mo, Al and X = P, As) and others containing M2O10 (M = Mo, Fe) dimers
Summary
Key indicators: single-crystal X-ray study; T = 298 K; mean (As–O) = 0.002 A; R factor = 0.013; wR factor = 0.039; data-to-parameter ratio = 10.4. Single crystals of trilithium(I) aluminium(III) bis[dioxidomolybdenum(VI)] dioxide bis[arsenate(V)], Li3AlMo2As2O14, have been prepared by solid-state reaction at 788 K. The structure consists of AsO4 tetrahedra, AlO6 octahedra and Mo2O10 groups sharing corners to form a three-dimensional framework containing channels running respectively along the [100] and [010] directions, where the Li+ ions are located. This structure is compared with compounds having (MX2O12)n chains (M = Mo, Al and X = P, As) and others containing M2O10 (M = Mo, Fe) dimers
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
