Abstract

Ionic diffusion and conductivity in Li 2CuO 2 and LiCuO 2 have been studied by complex impedance measurements. The conductivity of both samples is largely enhanced with increasing temperature and reaches 10 − 2 –10 − 1 S/m at around 450 K. X-ray diffraction measurements show that a small amount of CuO phase appears with increasing temperature in both samples. High electric conduction would be ascribed to a complicated mechanism containing the ionic and hole conduction.

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