Abstract
Poly(vinyl acetate), poly(vinylidene fluoride–hexafluoropropylene), lithium perchlorate salt, and the different plasticizer-based gel polymer electrolytes were prepared by solvent-casting technique. The structural and the complex formation have been confirmed by X-ray diffraction spectroscopic analysis. Thermal stability of the different plasticizer-added electrolyte films has been analyzed by means of thermogravimetric analysis. Ionic conductivity of the electrolyte samples has been found as a function of temperature and the plasticizers. Among the various plasticizers, ethylene carbonate-based complexes exhibit maximum ionic conductivity value of the order of 10−4 Scm−1. Finally, the microstructure of the maximum ionic conductivity sample has been depicted with the help of scanning electron microscope analysis.
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