Abstract
We describe the synthesis and structures of o-C6F4(TeMes)2 (1) and o-C6F4(TeArF)2 (2, ArF = 3,5-(CF3)2C6H3)), two new bifunctional tellurides featuring an electron-withdrawing backbone. While 2 resisted methylation, 1 reacted with Me3O·BF4 in CH2Cl2 to afford o-C6F4(TeMes)(TeMeMes) ([3]+), a mixed-valent telluride/telluronium cation isolated as a tetrafluoroborate salt. Although attempts to methylate the second telluride have been unsuccessful, [3]+ readily catalyzes the hydrogenation of 2-phenyl-quinoline with Hantzsch ester. Comparison with simple telluronium cations including [ArF2TeMe]+ and [MesArFTeMe]+ confirms that the catalytic activity of these compounds originates from the presence of a tetravalent, cationic tellurium center.
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