Abstract

AbstractUnsaturated fatty compounds such as oleic acid, which are of interest as renewable raw materials, can be functionalized at the C,C‐double bond by Lewis acid induced addition reactions. The products are branched and highly functionalized fatty compounds which may have interesting properties. SnCl4‐induced additions of nitriles to methyl oleate and ethyl 10‐undecenoate give the corresponding esters of the N‐acylamino fatty acids. Alkylaluminium halide induced ene additions of formaldehyde to unsaturated fatty compounds yield primary homoallylic alcohols. β,γ‐Unsaturated ketones are obtained in ethylaluminium dichloride induced Friedel‐Crafts acylations of unsaturated fatty compounds with acyl chlorides and cyclic anhydrides.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.