Abstract

Knowledge of contaminant distribution is important, particularly in the vulnerable first results about the occurrence of seventeen polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans and twelve dioxin-like polychlorinated biphenyls in arctic fjord seawater are reported. The contaminants were measured in 10 samples of suspended particulate matter collected in Hornsund (Svalbard). The ∑PCDD/F and ∑dl-PCB concentrations ranged from 0.066 to 231.47 pg/L and from 2.43 to 46.43 pg/L respectively. In terms of total PCDD/Fs, in general highly chlorinated PCDFs constituted the most significant fraction. Among dl-PCB compounds, PCB118 was the dominant congener. The toxicity equivalent for the samples ranged from 0.0008 to 1.90 pg I-TEQ/L for ∑PCDD/Fs, while for ∑dl-PCB it ranged from 0.0002 to 0.024 pg WHO05-TEQ/L. High concentrations of dioxins and dl-PCBs in some samples indicated that those contaminants could pose a threat to marine biota.

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