Levels and Composition of Atmospheric Particulates (PM10) in a Mining-Industrial Site in the City of Lavrion, Greece

Abstract

The present work focuses on the characterization of air quality and the identification of pollutant origin at a former mining site in the city of Lavrion, Greece. A historical metallurgy complex is reused for establishing the Lavrion Technology and Cultural Park (LTCP). A serious problem with this is the severe soil contamination that resulted from intensive mining and metallurgical activities that has taken place in the greater area for the past 3000 years. Among other consequences, surface-polluted depositions, rich in heavy and toxic metals, are loose and easily wind-eroded, resulting in transportation of particu-late matter (PM) in the surrounding atmosphere. On the other hand, there are a number of industries relatively close to the site that are potential sources of PM air pollution. The current study deals with the collection and analysis of PM10 samples with respect to their concentration in heavy metals, such as Pb, Cd, Cu, Fe, Zn, Mn, Cr, and Ni. Though not a heavy metal, As also is included. Furthermore, the source of these elements is verified using statistical correlation and by calculating enrichment factors (EFs), considering that some substances are certainly of contaminated soil origin. Results show that PM10 and element concentrations are relatively low during winter but significantly increase during summer. Fe, Pb, Zn, Mn, and Cu may be considered of contaminated soil origin, while As, Ni, Cd, and Cr are very much enriched with respect to contaminated soil, indicating another possible source attributed to the adjacent industrial plants.