Abstract

The crystal structure of a methanol–water solvate ofleurosine me­thio­dide, (leurosine-CH3)+I−·3CH3OH·2H2O (C47H59IN4O9·3CH3OH·2H2O), is described. The piperidine ring of the upper part of the mol­ecule adopts a sofa conformation. An intramolecular hydrogen bond between the tertiary N and the hydroxyl group of the vindoline moiety of the mol­ecule is present.

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