Abstract
A general survey of alkali metals intercalation compounds with titanium and zirconium disulfides is given. A model A + x (Ti S 2 x− or A + (Zr S 2) x− with an electronic delocalization in the (Ti 2S 2) or (Zr S 2) slabs, is suggested according to crystallographic and magnetic studies, N.M.R. measurements, and chemical behaviour. The alkali metal coordination is related to several factors: size of the A + ion, value of the x parameter, strength of the T.S. bonds.
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