Abstract
For N–H ⋯ N hydrogen bonds, the dependence of the N–H length on the H ⋯ N distance is studied using neutron diffraction data; this dependence is the same for both charged and uncharged N–H donors; geometry predictions for strong hydrogen bonds and values for the shortest possible N ⋯ N and N ⋯ O separations are deduced on the basis of the bond valence concept.
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