Abstract

Summary A method is proposed to calculate the areal compositional variations in large hydrocarbon reservoirs in the presence of thermal gradients. A model is developed from the fundamental equations of change for a multicomponent reservoir fluid mixture in a porous medium. The fluxes are obtained from nonequilibrium thermodynamics, and expressions are derived for mass diffusion coefficients. The thermodynamic properties are calculated by use of the Peng-Robinson equation of state (PR-EOS). Under the condition of stationary state, the governing equations are solved by use of the least-squares finite-element method (LSFEM) subject to specified sampling concentrations as data at several well sampling sites. The results are in good agreement with validation simulations based on a similar finite difference solution.

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