Abstract

Wettability and retention capacity of leaf surfaces are parameters that contribute to interception of rain, fog or dew by forest canopies. Contrary to common expectation, hydrophobicity or wettability of a leaf do not dictate the stickiness of drops to leaves. Crucial for the adhesion of drops is the contact angle hysteresis, the difference between leading edge contact angle and trailing edge contact angle for a running drop. Other parameters that are dependent on the static contact angle are the maximum volume of drops that can stick to the surface and the persistence of an adhering drop with respect to evaporation. Adaption of contact angle and contact angle hysteresis allow one to pursue different strategies of drop control, for example efficient water shedding or maximum retention of adhering water. Efficient water shedding is achieved if contact angle hysteresis is low. Retention of (isolated) large drops requires a high contact angle hysteresis and a static contact angle of 65.5°, while maximum retention by optimum spacing of drops necessitates a high contact angle hysteresis and a static contact angle of 111.6°. Maximum persistence with respect to evaporation is obtained if the static contact angle amounts to 77.5°, together with a high contact angle hysteresis. It is to be expected that knowledge of these parameters can contribute to the capacity of a forest to intercept water.

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