Lead isotopic fingerprinting as a tracer to identify the sources of heavy metals in sediments from the Four Rivers’ inlets to Dongting Lake, China

Abstract

In this study, Pb isotopic composition of bulk sediments and 1 M HCl leachates/residues of samples from the Four Rivers’ inlets to Dongting Lake (China) was determined to identify and differentiate the source of Pb inputs. Results highlighted that Xiangjiang river (XY-QS) sediments were highly enriched in Pb with less radiogenic Pb isotopes (e.g., 206Pb/207Pb ratios of 1.1830 ± 0.003), indicating the predominance of anthropogenic Pb inputs. In contrast, sediments of the Zijiang, Yuanjiang and Lishui rivers (ZD-LH) were moderately enriched in Pb and exhibited more radiogenic Pb (e.g., 206Pb/207Pb ratios of 1.1880 ± 0.008). Results from 1 M HCl extraction of XY-QS sediments illustrated that anthropogenic Pb was removed, which resulted in differentiation of 206Pb/207Pb isotope ratios between leachates (1.1740 ± 0.005) and residues (1.1846 ± 0.008), however, this difference was not observed in ZD-LH sediments (leachates: 1.1887 ± 0.009; residues: 1.1887 ± 0.008). Residual Pb isotope ratios suggested that Pb isotopic composition of lithologically inherited Pb in inlet sediments was similar, which was attributed to mixing, hydrological sorting, and averaging of different Pb sources from diverse geological settings. Pb isotopic tracing showed that Pb in XY-QS sediments resulted from the mixing of two end member sources, an anthropogenic source (less radiogenic Pb) from downstream ore smelting and upstream ore mining activities (53%) and a lithological source (37%) from granite through weathering. In contrast, Pb in ZD-LH sediments resulted from the mixing of multiple sources including Pb from upstream mining activities (20%), coal combustion (20%), and lithologically inherited Pb (60%) while surface sediments from the Yuanjiang river contained Pb from diesel oil usage (50%). Results from this study highlight the utility of a Pb isotope approach for identifying and differentiating Pb source inputs in diverse sediments from the Four River inlets to Dongting Lake (China).