Lead in Preserved Duck Eggs: Field Screening Test and Confirmation and Quantitation by Atomic Absorption Spectrophotometry and Anodic Stripping Voltammetry

Abstract

Analysis of preserved duck eggs in this laboratory by acid digestion and atomic absorption spectrophotometry has shown that addition of lead salts to the egg coating to speed the preservation process results in lead in the egg albumen and yolk. The lead levels decrease as the lead passes through successive membranes, i.e., the lead level in the yolk is lower than that in the albumen. A method has been developed for the field screening of preserved duck eggs for the presence of lead in which a portion of the egg coating is shaken with 4% acetic acid, and the resulting solution is tested by a modification of the AOAC dithizone method. A quantitative method for laboratory confirmation of lead in egg albumen and/or yolk has also been developed in which lead is determined by atomic absorption spectrophotometry or anodic stripping voltammetry after closed-system Teflon-cup digestion with nitric acid.