Leaching of manganese from low-grade manganese ore using oxalic acid as reductant in sulphuric acid solution

Abstract

Leaching studies of low-grade Joda manganese ore containing 24.7% Mn and 28.4% Fe were carried out at high temperature and atmospheric pressure using oxalic acid as reductant in sulphuric acid medium. The experiments were designed according to 2 4 full factorial design, and regression equations for extraction of manganese, iron and aluminum were determined from the data. All the significant main and interaction effects on extraction of Mn, Fe and Al have positive effect, except oxalic acid concentration and time interaction for extraction of Al. Oxalic acid concentration has strongest effect on extraction of Mn, whereas temperature and time have strongest effect on extraction of Fe and Al, respectively. 98.4% Mn and 8.7% Fe were extracted from −150+105 μm ore with 30.6 g/l oxalic acid, 0.543 M sulphuric acid concentration at 85 °C in 105 min.