Abstract

Coal and host rock, including the gangue dump, are important sources of toxic elements, which have high-contaminating potential to surface and groundwater. Surface water in the coal mine area and groundwater in the active or abandoned coal mines have been observed to be polluted by trace elements, such as arsenic, mercury, lead, selenium, cadmium. It is helpful to control pollution caused by the trace elements by understanding the leaching behavior and mechanism. The leaching and migration of the trace elements are controlled mainly by two factors, trace elements’ occurrence and the surrounding environment. The traditional method to investigate elements’ occurrence and leaching mechanism is based on the geochemical method. In this research, the data mining method was applied to find the relationship and patterns, which is concealed in the data matrix. From the geochemical point of view, the patterns mean the occurrence and leaching mechanism of trace elements from coal and host rock. An unsupervised machine learning method, principal component analysis was applied to reduce dimensions of data matrix of solid and liquid samples, and then, the re-calculated data were clustered to find its co-existing pattern using the method of Gaussian mixture model.

Highlights

  • Coal is a complex system, which contains most elements in the periodic table

  • A total of 16 water samples were collected from the study site, including 12 coal mine waters, two surface waters, and two carbonate waters, respectively

  • It is found that Se, Cd, Hg, and As were associated with sulfide minerals; Be and V occurred in carbonate minerals; Cr and Pb occurred mainly in clay minerals in the rock samples

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Summary

Introduction

Coal is a complex system, which contains most elements in the periodic table. The origin of the coal was organic matter containing virtually every element, mainly carbon, and trace elements. The elements with relative higher content in the coal and host rock, such as iron (Fe) and aluminum (Al), which usually take 1–20% of the rock, respectively, and sodium (Na), potassium (K), calcium (Ca), magnesium (Mg), which are usually in the range of 0.01–10% of the rock, respectively. The trace elements refer to the elements at the 10–10,000 ppm levels in coal, rocks, and soil, etc. Some of the trace elements are of great health concern. Lead (Pb) accounts for most of the cases of pediatric heavy metal poisoning and makes it difficult for children to learn, pay attention, and succeed in school. Arsenic (As) could cause heavy metal poisoning in adults and does not leave the body once it enters

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