Abstract

In order to evaluate the environmental risk caused by land application of sewage sludge, leaching characteristics of heavy metals and plant nutrients in the sewage sludge immobilized by composite phosphorus-bearing materials were investigated. Their cumulative release characteristics were confirmed. Furthermore, the first-order kinetics equation, modified Elovich equation, double-constant equation, and parabolic equation were used to explore dynamic models of release. Results showed that sewage sludge addition significantly increased electricity conductivity (EC) in leachates, and the concentrations of heavy metals (Cu, Cr, Zn) and plant nutrients (N, P, K) were also obviously increased. The highest concentrations of Cu, Cr, and Zn in the leachates were all below the limit values of the fourth level in the Chinese national standard for groundwater quality (GB/T14848-2017). The immobilization of composite phosphorus-bearing materials reduced the release of Cu and Cr, while increased that of Zn. The fitting results of modified Elovich model and double-constant model were in good agreement with the leaching process of heavy metals and plant nutrients, indicating their release process in soil under simulated leaching conditions was not a simple first-order reaction, but a complex heterogeneous diffusion process controlled by multifactor.

Highlights

  • Sewage sludge is a residue produced during the biological wastewater treatment process

  • Sewage sludge is rich in organic matter (OM), nitrogen (N), phosphorus (P), and other trace elements such as

  • PH values increased with the increase of leachate volume, and achieved their maximum values, which were 7.35, 7.57, and 7.60 in the control treatment, stabilized sewage sludge treatment (SSS) treatment, and unstabilized sewage sludge treatment (USS) treatment, respectively, when the collected leachate reached 1.2 L (Figure 1)

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Summary

Introduction

Sewage sludge is a residue produced during the biological wastewater treatment process. Sewage sludge is rich in organic matter (OM), nitrogen (N), phosphorus (P), and other trace elements such as. Its land application can effectively utilize the useful resources and provide an important and low-cost alternative for sewage sludge disposal [3,4]. The properly treated sewage sludge is commonly used to improve soil quality [5,6]. Hamdi et al conducted a field study over a three-year period under a semi-arid climate and found that repetitive sludge addition consistently improved total organic carbon (TOC), N, P, and K content up to soils treated with 120 t·ha−1 ·year−1 , and impacted positively on biological properties, including microbial biomass and soil enzyme activities [7].

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