Abstract
The electronic transition B2Π–X2Π of PS has been studied in the region 3450–5700 Å. One hundred fourteen sub-bands have been put in the vibrational classification. They arise from 13 levels (ν = 0 to 12) of the B2Π state and from 10 levels (ν = 0 to 9) of the X2Π state.The rotational analysis of 50 sub-bands allows the determination of the equilibrium constants of the two states and presents the perturbations in the levels ν > 9 of the B2Π state.
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