Layer-by-layer printable nano-scale polypropylene for precise control of nanocomposite capacitor dielectric morphologies in metallised film capacitors

Abstract

• A novel technique to fabricate capacitors with nano-scale layer-by-layer printing • Polypropylene gel inks were used to successively print layers as thin as 200 nm • Layer thickness is easily controllable, and the capacitance is highly predictable • Incorporation of BaTiO 3 nanoparticles was demonstrated in a structured dielectric • Presents pathway to the commercial printing of structured nanocomposite capacitors Nanocomposite dielectrics are an increasingly important area of innovation in capacitor research as an avenue to improve capacitive energy density, electrical breakdown strength, and temperature stability of devices. In such devices, morphology control is critical in order to optimise electrical field distribution in the device and to prevent the clustering of nanoparticles lowering breakdown voltages. However, this is difficult to achieve with large-scale fabrication techniques, such as melt extrusion and stretching, as melt processing can induce clustering and offers few possibilities for fine structure control of length scales below 1 µm. Layer-by-layer fabrication offers a potential bottom-up alternative whereby dielectrics are printed by successive depositions of ultra-thin layers of a room-temperature-stable polymer ink. This would allow fine thickness and morphology control and could easily be adapted to industrial-scale printing techniques, like roll-to-roll slot-die coating. This study explores this technique by developing two polypropylene-based inks in industry-friendly solvents that are then used to fabricate capacitor devices. A gel ink was able to be used to deposit ultrathin (sub-200 nm) layers of mostly amorphous polypropylene with high reproducibility. Capacitors based on these polypropylene layers perform commensurate with commercial devices, exhibiting excellent self-clearing and breakdown performance. Successive depositions of the ink were also demonstrated, allowing the fabrication of devices with finely tuned thicknesses and capacitances, as well as nanocomposite capacitors. This demonstrates the viability of layer-by-layer dielectric printing at large scale and paves the way for commercial ultra-thin conformable polypropylene capacitors, multi-component sandwich nanocomposite capacitors, and multilayer polypropylene capacitors, as well as brand new possibilities in dielectrics research.