Lattice strain controlled Ni@NiCu efficient anode catalysts for direct borohydride fuel cells.

Abstract

We successfully fabricated a novel tensile lattice strained Ni@NiCu catalyst with a popcorn-like morphology, which is composed of a crystalline Ni core and a NiCu alloy shell. It exhibits outstanding catalytic activity, selectivity, and stability towards borohydride electrooxidation. Moreover, a direct borohydride fuel cell (DBFC) with a Ni@NiCu anode can deliver a power density of 433 mW cm-2 and an open circuit voltage of 1.94 V, much better than the performances of DBFCs employing other anode catalysts reported in the literature. This could be attributed to the fact that the tensile lattice strain generated by the introduction of Cu leads to a rise in the d-band center of the Ni metal and promotes the final B-H decoupling, which is the rate-determining step in the borohydride oxidation reaction, thus improving remarkably the catalytic performances of Ni@NiCu.