Abstract
NbSi 2, TaSi 2 and VSi 2 phonon properties have been investigated at 300 K using inelastic neutron scattering and Raman scattering. The results are reported and compared to previous results obtained by other techniques such as point-contact spectroscopy. Inelastic neutron scattering on powders allowed us to separate longitudinal and transverse acoustic from optical modes, especially for TaSi 2 and NbSi 2. The acoustic modes are shifted towards higher energy when decreasing the molar mass of the compound. Triple axis inelastic neutron scattering on NbSi 2 single crystal led to more detailed information about the phonon spectrum. The energy of most of the modes has been followed all along the first Brillouin zone. Raman scattering measurements carried out on NbSi 2 single crystals allowed us to obtain the energy at the Brillouin zone center and the symmetry assignment of all the Raman active modes.
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