Abstract
On the basis of the polarizable-ion model (PIM) the effect of the width of the atomic electron distribution on the lattice dynamics of α-quartz was taken into account using the Birman method. The frequencies of optical mode, elastic constants and piezoelectric constants were reproduced using the parameters of this model (an effective charge z, a width parameter w, an electronic polarizability α, and force constants). The width parameter of oxygen atom was found to be about 0.59 A, and the effective charge of the silicon atom 1.42 electron charges.
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